CSEC Chemistry · January 2012 · Paper 2
48 questions and parts from this paper. Open one to see it in full, then practise it on Quelpr and get it marked against the mark scheme.
- 1(a)(i)2 marksDefine the term 'heat of neutralization'.
- 1(a)(ii)3 marksUse the data in Table 1 to plot a graph of temperature against volume of acid for Experiment 1 using the axes provided on page 5. The first two points have been plotted for you.
- 1(a)(iii)1 markFrom the graph, determine the volume of sulphuric acid required to completely neutralize 25 cm³ of sodium hydroxide.
- 1(a)(iv)3 marksGiven that the difference in temperature from the start of the reaction to the point of neutralization is 18 °C, calculate the heat change at the point of neutralization for the reaction between sodium hydroxide and…
- 1(b)(i)2 marksDefine the term 'heat of solution'.
- 1(b)(ii)1 markFigure 2 shows the thermometer readings for the initial and final temperatures obtained for Experiment 2. Record the reading, in °C, on each thermometer in the space provided.
- 1(b)(iii)3 marksWrite a suitable procedure that could be carried out for Experiment 2.
- 1(b)(iv)3 marksDraw a labelled energy profile diagram for the reaction taking place in Experiment 2.
- 1(c)(i)2 marksWrite a balanced half-equation to represent the change which takes place when Solution X reacts with aqueous iron(II) nitrate.
- 1(c)(ii)3 marksExplain whether Solution X is behaving as a reducing agent, an oxidizing agent or both.
- 1(c)(iii)2 marksDescribe Observation 3 as indicated in Table 2.
- 2(a)2 marksAssuming that the limestone granules are pure calcium carbonate, write a balanced equation for its reaction with hydrochloric acid.
- 2(b)(i)1 markUse the data from Figure 3 to determine the total volume of gas produced.
- 2(b)(ii)1 markto calculate the moles of gas produced at STP [1 mole of any gas at STP has a volume of 22 400 cm³.]
- 2(b)(iii)2 marksto calculate the mass of limestone granules used. [Relative molecular mass of CaCO₃ is 100.]
- 2(c)(i)1 markWhat is meant by the term 'rate of reaction'?
- 2(c)(ii)2 marksBesides temperature, identify TWO other factors that can affect the rate of the reaction.
- 2(c)(iii)a)1 markIf the temperature at which the reaction was carried out was changed from 25 °C to 40 °C, would the rate of reaction increase or decrease?
- 2(c)(iii)b)2 marksExplain your answer.
- 2(d)(i)1 markIs it LIKELY that calcium carbonate will conduct electricity in its solid state?
- 2(d)(ii)2 marksGive a reason for your answer.
- 3(a)2 marksHydrocarbons are compounds that contain the elements, hydrogen and carbon. Name TWO natural sources of hydrocarbons.
- 3(b)(i)1 markState the name of Fraction 1 OR Fraction 3. Fraction number: Fraction name:
- 3(b)(ii)1 markState ONE use of Fraction 2.
- 3(c)(i)1 markState the name of Compound X and the homologous series to which it belongs. Name of Compound X: Homologous series:
- 3(c)(ii)2 marksWrite the FULLY DISPLAYED structural formulae of the two molecules that are produced when Compound X is hydrolysed.
- 3(d)(i)a)1 markName a polymer of glucose. Name of polymer:
- 3(d)(i)b)2 marksUsing three glucose units, draw the partial structure of the polymer in the space provided.
- 3(d)(ii)2 marksState the expected observations in EACH case. Glucose: Polymer:
- 3(e)1 markName the type of polymer formed and give ONE use for this type of polymer. Type of polymer: Use:
- 4(a)(i)2 marksWrite the electronic configuration of sodium and state a reason for its placement in Period 3.
- 4(a)(ii)a)2 marksWrite a balanced equation for the reaction of sodium with water.
- 4(a)(ii)b)2 marksOutline ONE test that can be used to identify any gas that is produced during the reaction.
- 4(a)(ii)c)1 markPredict the reactivity of X with water as compared with sodium and potassium.
- 4(a)(iii)2 marksGive ONE test that can be used to distinguish the solution of the oxide of Element Y from the solution of the oxide of sulphur.
- 4(b)(i)4 marksWrite a balanced IONIC equation for the overall reaction, and identify the species being oxidised and reduced.
- 4(b)(ii)2 marksAccount for the difference in reactivity of chlorine and iodine towards iron(II).
- 5(a)(i)6 marksDescribe the process for obtaining iron from its ore. In your description, identify the materials used and include a chemical equation to show how iron is produced.
- 5(a)(ii)1 markCarbon and carbon monoxide are both able to reduce the oxide ore to produce iron. Suggest a suitable explanation why carbon monoxide is used to reduce the iron ore instead of carbon.
- 5(b)(i)a)4 marksWrite suitable equations for the action of heat on the hydroxide of M.
- 5(b)(i)b)4 marksWrite suitable equations for the action of heat on the nitrate of M.
- 5(b)(ii)3 marksSuggest a suitable method for extracting Metal M from its ore and explain your answer.
- 5(b)(iii)1 markSuggest ONE chemical property of Metal M.
- 6(a)(i)2 marksDiscuss the role of Water in the making of dough:
- 6(a)(ii)2 marksDiscuss the role of Leavening agent (baking powder and yeast) in the making of dough:
- 6(a)(iii)2 marksDiscuss the role of Heat in the making of dough:
- 6(b)6 marksWrite THREE relevant chemical equations to support your answer in (a). Include AT LEAST ONE equation from the action of yeast and ONE from the action of baking powder.
- 6(c)3 marksSuggest a possible explanation for this.