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3 marksEnergetics

CSEC Chemistry · January 2012 · Paper 2 · Question 1(a)(iv)

Students conducted Experiment 1 to determine the heat of neutralization for the reaction between sodium hydroxide and sulfuric acid. The procedure involved measuring 25 cm³ of dilute sodium hydroxide into a styrofoam cup and 25 cm³ of sulfuric acid into a burette. Both solutions were left to reach room temperature before recording their initial temperatures. Sulfuric acid was added to the sodium hydroxide solution 3 cm³ at a time, with the mixture stirred after each addition, and the maximum temperature recorded in Table 1.

Given that the difference in temperature from the start of the reaction to the point of neutralization is 18 °C, calculate the heat change at the point of neutralization for the reaction between sodium hydroxide and sulphuric acid. [The specific heat capacity of the solution is 4.2 kJ kg⁻¹ K⁻¹. Assume that the density of the solution is 1g cm⁻³, ΔH = m × c × ΔT.]

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Other parts of this question

  1. 1(a)(i)Define the term 'heat of neutralization'.[2 marks]
  2. 1(a)(ii)Use the data in Table 1 to plot a graph of temperature against volume of acid for Experiment 1 using the axes provided on page 5. The first two points have…[3 marks]
  3. 1(a)(iii)From the graph, determine the volume of sulphuric acid required to completely neutralize 25 cm³ of sodium hydroxide.[1 mark]
  4. 1(b)(i)Define the term 'heat of solution'.[2 marks]
  5. 1(b)(ii)Figure 2 shows the thermometer readings for the initial and final temperatures obtained for Experiment 2. Record the reading, in °C, on each thermometer in the…[1 mark]
  6. 1(b)(iii)Write a suitable procedure that could be carried out for Experiment 2.[3 marks]
  7. 1(b)(iv)Draw a labelled energy profile diagram for the reaction taking place in Experiment 2.[3 marks]
  8. 1(c)(i)Write a balanced half-equation to represent the change which takes place when Solution X reacts with aqueous iron(II) nitrate.[2 marks]
  9. 1(c)(ii)Explain whether Solution X is behaving as a reducing agent, an oxidizing agent or both.[3 marks]
  10. 1(c)(iii)Describe Observation 3 as indicated in Table 2.[2 marks]

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