Quelpr

CSEC Chemistry · May/June 2019 · Paper 2 · Question 1(a)(ii)

Michael and Jennifer investigated the effect of surface area on the rate of reaction between zinc metal (Zn) and dilute sulfuric acid (H₂SO₄). They used six different grades of granulated zinc, representing average radius sizes (in microns, µm). Six experiments were conducted using these zinc grades, reacting them with an excess of 0.5 mol dm⁻³ dilute sulfuric acid at 25 °C. The same mass (0.55 g) of zinc granules was used in all experiments. The time taken to collect 100 cm³ of hydrogen gas was recorded. Figure 1 shows stopwatch readings for Experiments 1-6, and Table 1 on page 6 provides some data.

Using the formula Rate = 1/Time, calculate the rate of reaction for each experiment and record these values to 3 decimal places in Column 4 of Table 1. The rate of reaction for Experiment 1 has already been calculated for you.

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Other parts of this question

  1. 1(a)(i)From the stopwatches displayed in Figure 1 on page 5, record the times for the hydrogen gas to be collected in Column 3 in Table 1. The time taken for…[3 marks]
  2. 1(a)(iii)Using the grid provided on page 7, plot a graph of rate versus time for Experiments 1-6. Draw the best curve through the points.[5 marks]
  3. 1(b)(i)Based on the graph plotted on page 7, deduce how the rate of the reaction varied with time.[2 marks]
  4. 1(b)(ii)Explain how the trend in the rate of reaction stated in (b)(i) relates to the surface area of the zinc granules.[2 marks]
  5. 1(b)(iii)List THREE factors, other than surface area, that affect the rate of a reaction.[3 marks]
  6. 1(c)State ONE safety precaution that Michael and Jennifer may have taken during the experiments.[1 mark]
  7. 1(d)Suggest ONE way in which Michael and Jennifer may have controlled the temperature during the experiments.[1 mark]
  8. 1(e)(i)Write a balanced chemical equation, including state symbols, for the reaction between zinc metal and sulfuric acid.[2 marks]
  9. 1(e)(ii)Calculate the total volume of hydrogen gas that would be produced at RTP from 0.55 g of zinc granules. [RAM: Zn = 65.4; 1 mole of a gas occupies 24 000 cm³ at…[3 marks]

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