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CSEC Chemistry · May/June 2008 · Paper 2 · Question 1(a)(v)a)

A strong acid-base titration is performed, and pH changes are measured using a pH meter to determine the end point. The end point is expected to be a sharp pH change at 7.0. Figure 1 shows ten pH readings from an experiment where 20.0 cm³ of 0.005 mol dm⁻³ sulphuric acid is titrated with sodium hydroxide of unknown concentration. Reading I is the initial pH of the sulphuric acid, and readings II to X are pH values after adding various volumes of sodium hydroxide, as indicated in Figure 1.

Calculate EACH of the following: The number of moles of sulphuric acid in 20 cm³ of the sulphuric acid used

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Other parts of this question

  1. 1(a)(i)a)What is meant by EACH of the following? pH scale[4 marks]
  2. 1(a)(i)b)What is meant by EACH of the following? The end point of an acid-base titration[4 marks]
  3. 1(a)(ii)Complete Table 1 below by recording the missing pH meter readings from Figure 1.[2 marks]
  4. 1(a)(iii)Using the graph paper provided on page 5 and the data in Table 1, plot a graph of pH against volume of sodium hydroxide added.[3 marks]
  5. 1(a)(iv)Use the graph to determine the volume of sodium hydroxide which reacts completely with the 20 cm³ of 0.005 mol dm⁻³ sulphuric acid.[1 mark]
  6. 1(a)(v)b)Calculate EACH of the following: The number of moles of sodium hydroxide in the volume of sodium hydroxide used in (a) (iv)[2 marks]
  7. 1(a)(v)c)Calculate EACH of the following: The number of moles of sodium hydroxide in 1 dm³ of this solution[1 mark]
  8. 1(b)Complete Table 2 by filling in the inferences that could be made based on the observations recorded.[1 mark]
  9. 1(c)Plan and design an experiment to determine which of the four catalysts above will be most effective in increasing the rate of decomposition of hydrogen…[2 marks]
  10. 1(c) (diagram)Labelled diagram of apparatus to be used:[2 marks]

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